Bolaño García

Profesor/a titular de universidad

Área de Química Inorgánica
Departamento de Química Inorgánica

Información de contacto

Facultad de Química
Edificio de Ciencias Experimentais
Bloque E, Planta 3, Despacho 17

As Lagoas, Marcosende
36310 Vigo

+34 986 812 274
bgs@uvigo.es

Breve CV

Licenciada en Ciencias Químicas por la Universidad de Vigo en 1998. Doctora en Química por la Universidad de Vigo en 2003. Estancias de investigación en el grupo del Dr. Maurizio Peruzzini en la CNR-ICCOM (Firenze, Italia) 2003-2004, Prof.Dr. Alberto Albinati en Universitá degli Studi di Milano (Milán, Italia) 2004-2005, Prof. Dr. Alceo Machioni en Universitá degli Studi di Perugia (Perugia, Italia) 2007. Autor de 39 trabajos de investigación. Dirección de 2 Tesis Doctorales, 2 Tesis de Licenciatura y 2 proyectos de Tesis de Master. Participación en 6 proyectos de investigación, de los cuales uno de la Unión Europea y otro un Consolider-Ingenio. Colaboraciones con el grupo de investigación de Dr. Maurizio Peruzzini y del Prof. Dr. Alceo Machioni. Mi investigación se desarrolla dentro del área de Química Organometálica trabajé en síntesis y reactividad de hidrurocomplejos y complejos solubles en agua con aplicaciones en catálisis y en medicina. Actualmente mi línea de investigación se centra en la síntesis y estudio de nuevos sistemas metalaaromáticos para aplicaciones en ciencia de los materiales.

Investigación

Grupo de investigación

Nuevos Materiales

Líneas de investigación

  • Síntesis y estudio de nuevos sistemas metalaaromáticos para aplicaciones en ciencia de los materiales

 

Resultados de investigación

Article
Talavera, M., Pereira-Cameselle, R., Peña-Gallego, Á., Vázquez-Carballo, I., Prieto, I., Alonso-Gómez, J.L., Bolaño, S.,
Optical and electrochemical properties of spirobifluorene iridanaphthalene complexes
Dalton Transactions, 52, 2, 2022 | DOI

Article
Pereira-Cameselle, R., Peña-Gallego, Á., Cid-Seara, K.M., Alonso-Gómez, J.L., Talavera, M., Bolaño, S.,
Chemoselectivity on the synthesis of iridacycles: A theoretical and experimental study
Inorganica Chimica Acta, 517, , 2021 | DOI

Article
Talavera, M., Cid-Seara, K.M., Penã-Gallego, Á., Bolanõ, S.,
Key factors in the synthesis of polycyclic iridaaromatics: Via the methoxyalkenylcarbene pathway
Dalton Transactions, 50, 32, 2021 | DOI

Review
Talavera, M., Bolaño, S.,
Iridaaromatics via methoxy(Alkenyl)carbeneiridium complexes
Molecules, 26, 15, 2021 | DOI

Article
Arias-Coronado, V.C., Pereira-Cameselle, R., Ozcelik, A., Talavera, M., Peña-Gallego, Á., Alonso-Gómez, J.L., Bolaño, S.,
Spirobifluorene Metallaaromatics
Chemistry – A European Journal, 25, 59, 2019 | DOI

Article
Talavera, M., Peña-Gallego, A., Alonso-Gómez, J.L., Bolaño, S.,
Metallaaromatic biaryl atropisomers
Chemical Communications, 54, 78, 2018 | DOI

Article
Talavera, M., Pereira-Cameselle, R., Bolaño, S.,
Rhodafuran from a methoxy(alkenyl)carbene by the rhoda-1,3,5-hexatriene route
Dalton Transactions, 47, 27, 2018 | DOI

Article
Talavera, M., Bolaño, S., Bravo, J., García-Fontán, S., Hermida-Ramõn, J.M.,
The Catalytic Role of Extra Molecules in the Aminolysis or Heterolytic Cleavage of an Iridium Alkoxycarbene Complex
European Journal of Inorganic Chemistry, 2015, 24, 2015 | DOI

Article
Talavera, M., Bravo, J., Castro, J., García-Fontán, S., Hermida-Ramón, J.M., Bolaño, S.,
Electronic effects of substituents on the stability of the iridanaphthalene compound [IrCp?{C(OMe)CHC(o-C<inf>6</inf>H<inf>4</inf>)(Ph)}(PMe<inf>3</inf>)]PF<inf>6</inf>
Dalton Transactions, 43, 46, 2014 | DOI

Article
Talavera, M., Bravo, J., Gonsalvi, L., Peruzzini, M., Zuccaccia, C., Bolaño, S.,
[PF<inf>6</inf>]<inf>2</inf> As catalyst for the meyer-schuster rearrangement of arylpropargylic alcohols under mild conditions
European Journal of Inorganic Chemistry, 2014, 36, 2014 | DOI

Article
Talavera, M., Bolaño, S., Bravo, J., Castro, J., García-Fontán, S.,
Cyclometalated iridium complexes from intramolecular C-H activation of [IrCp*Cl{=C(OMe)CH=C(CH<inf>3</inf>)R}L] (R = CH<inf>3</inf>, Ph; L = PPh<inf>2</inf>Me, PMe<inf>3</inf>)
Organometallics, 32, 23, 2013 | DOI

Article
Talavera, M., Bolaño, S., Bravo, J., Castro, J., García-Fontán, S., Hermida-Ramón, J.M.,
Nucleophilic attack in methoxycarbenes: Heterolytic cleavage of the carbon (sp<sup>3</sup>)-oxygen bond versus aminolysis
Organometallics, 32, 15, 2013 | DOI

Article
Talavera, M., Bolaño, S., Bravo, J., Castro, J., García-Fontán, S., Hermida-Ramón, J.M.,
Formation of indanone from an iridanaphthalene complex
Organometallics, 32, 15, 2013 | DOI

Article
Talavera, M., Bolaño, S., Bravo, J., Castro, J., García-Fontán, S.,
Synthesis and characterization of new pentamethylcyclopentadienyl iridium hydride complexes
Journal of Organometallic Chemistry, 715, , 2012 | DOI

Article
Zuccaccia, C., Bellachioma, G., Bolaño, S., Rocchigiani, L., Savini, A., MacChioni, A.,
An NMR study of the oxidative degradation of Cp <sup>*</sup>ir catalysts for water oxidation: Evidence for a preliminary attack on the quaternary carbon atom of the -C-CH <inf>3</inf> moiety
European Journal of Inorganic Chemistry, , 9, 2012 | DOI

Article
Savini, A., Bellachioma, G., Bolaño, S., Rocchigiani, L., Zuccaccia, C., Zuccaccia, D., MacChioni, A.,
Iridium-EDTA as an efficient and readily available catalyst for water oxidation
ChemSusChem, 5, 8, 2012 | DOI

Article
Bolaño, S., Bravo, J., Castro, J., García-Fontán, S., Marín, M.C.,
New complexes of the fac-{(CO)<inf>3</inf>Re<sup>+</sup>} fragment bearing a diaminediphosphine ligand
Polyhedron, 29, 10, 2010 | DOI

Article
Ciancaleoni, G., Bolaño, S., Bravo, J., Peruzzini, M., Gonsalvi, L., MacChioni, A.,
Counterion-dependent deuteration of pentamethylcyclopentadiene in water-soluble cationic Rh(III) complexes assisted by PTA
Dalton Transactions, 39, 14, 2010 | DOI

Article
Bolaño, S., Bravo, J., Castro, J., García-Fontán, S., Marín, M.C.,
Synthesis and characterization of new chlorocarbonylrhenium(I) complexes with P-donor chelate ligands
Zeitschrift fur Anorganische und Allgemeine Chemie, 636, 3-4, 2010 | DOI

Review
Bravo, J., Bolaño, S., Gonsalvi, L., Peruzzini, M.,
Coordination chemistry of 1,3,5-triaza-7-phosphaadamantane (PTA) and derivatives. Part II. The quest for tailored ligands, complexes and related applications
Coordination Chemistry Reviews, 254, 5-6, 2010 | DOI

Article
Bolaño, S., Bravo, J., Castro, J., Rodríguez-Rocha, M.,
Formation of oxaphosphacarbenes by reaction of RuTpCl(PPh <inf>3</inf>)(thp)J with terminal alkynes and a propargylic alcohol
European Journal of Inorganic Chemistry, , 5, 2010 | DOI

Article
Bolaño, S., Plaza, M., Bravo, J., Castro, J., Peruzzini, M., Gonsalvi, L., Ciancaleoni, G., Macchioni, A.,
New highly water-soluble rhodium complexes bearing 1,3,5-triaza-7-phosphaadamantane (PTA) and/or tris(hydroxymethyl) phosphine (THP)
Inorganica Chimica Acta, 363, 3, 2010 | DOI

Article
Bolaño, S., Bravo, J., Castro, J., García-Fontan, S., Lamas, E., Seoane, P.R.,
Synthesis and characterization of Di- and Tricarbonylhydridomanganese(I) complexes
Zeitschrift fur Anorganische und Allgemeine Chemie, 635, 15, 2009 | DOI

Article
Bolaño, S., Mar Rodríguez-Rocha, M., Bravo, J., Castro, J., Oñate, E., Peruzzini, M.,
Reactivity of [TpRuCl(PTA)(PPh<inf>3</inf>)] with alkynes and propargylic alcohols: Occurrence of structurally related cationic vs neutral allenylidene complexes with the ruthenium hydrotris(pyrazolyl)borate moiety
Organometallics, 28, 20, 2009 | DOI

Article
Bolaño, S., Bravo, J., Castro, J., del Carmen Marín, M., García-Fontán, S.,
Synthesis, characterization and crystal structure of cis,mer-[ReH(CO)<inf>2</inf>{PPh(OMe)<inf>2</inf>}<inf>3</inf>]
Inorganic Chemistry Communications, 12, 9, 2009 | DOI

Article
Bolaño, S., Bravo, J., Fernández-García, F., García-Fontán, S., del Carmen Marín, M.,
Hydride and dihydrogen dicarbonylrhenium(I) complexes with phosphites, phosphonites and phosphinites
Journal of Organometallic Chemistry, 694, 18, 2009 | DOI

Article
Bolaño, S., Bravo, J., Castro, J., García-Fontán, S., Rodríguez, M.C.,
Synthesis and characterization of rhenium carbonyltrifluoroacetate complexes with phosphites, phosphonites and phosphinites
Polyhedron, 28, 12, 2009 | DOI

Article
Caporali, M., Barbaro, P., Bolaño, S., Gonsalvi, L., Carpioc, S.M., Peruzzini, M.,
NMR studies on the novel heterobimetallic complexes [M(dppm)(Ph <inf>2</inf>PCH<inf>2</inf>PPh<inf>2</inf>PPPP) {Pt(PPh<inf>3</inf>) <inf>2</inf>}]OTf (M = Rh, Ir) derived from the stepwise activation of white phosphorus
Magnetic Resonance in Chemistry, 46, SUPPL. 1, 2008 | DOI

Article
Bolaño, S., Bravo, J., Castro, J., García-Fontán, S., Marín, M.C.,
Synthesis, characterization and crystal structure of fac-[Re(H<inf>2</inf>O)(CO)<inf>3</inf>{Ph<inf>2</inf>PO(CH<inf>2</inf>) <inf>3</inf>OPPh<inf>2</inf>}]BAr<inf>F</inf>
Inorganic Chemistry Communications, 11, 9, 2008 | DOI

Article
Caporali, M., Bianchini, C., Bolaño, S., Bosquain, S.S., Gonsalvi, L., Oberhauser, W., Rossin, A., Peruzzini, M.,
Synthesis and characterisation of ?<sup>1</sup>-P and ?<sup>2</sup>-P,N palladium(II) complexes of the open cage water soluble aminophosphine PTN
Inorganica Chimica Acta, 361, 11, 2008 | DOI

Article
Bolaño, S., Albinati, A., Bravo, J., Caporali, M., Gonsalvi, L., Male, L., Mar Rodríguez-Rocha, M.a., Rossin, A., Peruzzini, M.,
Synthesis and reactivity of rhodium(III) pentamethylcyclopentadienyl complexes of N-B-PTA(BH<inf>3</inf>): X-ray crystal structures of [Cp<sup>*</sup>RhCl<inf>2</inf>{N-B}-PTA(BH<inf>3</inf>)] and [Cp<sup>*</sup>Rh{N-B-PTA(BH<inf>3</inf>)}(?<sup>2</sup>-CH<inf>2</inf> = CHPh)]
Journal of Organometallic Chemistry, 693, 14, 2008 | DOI

Article
Bolaño, S., Ciancaleoni, G., Bravo, J., Gonsalvi, L., Macchioni, A., Peruzzini, M.,
PGSE NMR studies on RAPTA derivatives: Evidence for the formation of H-bonded dicationic species
Organometallics, 27, 7, 2008 | DOI

Article
Bolaño, S., Bravo, J., Castro, J., Rodríguez-Rocha, M.M., Guedes Da Silva, M.F.C., Pombeiro, A.J.L., Gonsalvi, L., Peruzzini, M.,
Synthesis, reactivity, X-ray crystal structures and electrochemical behaviour of water-soluble [tris(pyrazolyl)borato]ruthenium(II) complexes of 1,3,5-triaza-7-phosphaadamantane (PTA)
European Journal of Inorganic Chemistry, , 35, 2007 | DOI

Article
Dorcier, A., Ang, W.H., Bolano, S., Gonsalvi, L., Juillerat-Jeannerat, L., Laurenczy, G., Peruzzini, M., Phillips, A.D., Zanobini, F., Dyson, P.J.,
In vitro evaluation of rhodium and osmium RAPTA analogues: The case for organometallic anticancer drugs not based on ruthenium
Organometallics, 25, 17, 2006 | DOI

Article
Pelagatti, P., Bacchi, A., Balordi, M., Bolaño, S., Calbiani, F., Elviri, L., Gonsalvi, L., Pelizzi, C., Peruzzini, M., Rogolino, D.,
Octahedral Ru<sup>II</sup> complexes with [PNO] hydrazonic ligands: Synthesis, structure, reactivity and catalytic activity in the addition of benzoic acid to alkynes
European Journal of Inorganic Chemistry, , 12, 2006 | DOI

Article
Phillips, A.D., Bolaño, S., Bosquain, S.S., Daran, J.C., Malacea, R., Peruzzini, M., Poli, R., Gonsalvi, L.,
A new class of rhodium(I) ?.<sup>1</sup>-P and ?<sup>2</sup>-P, N complexes with rigid PTN(R) ligands (PTN = 7-phospha-3-methyl-1,3,5- triazabicyclo[3.3.1]nonane)
Organometallics, 25, 9, 2006 | DOI

Article
Bolaño, S., Albinati, A., Bravo, J., Gonsalvi, L., Peruzzini, M.,
Borane adducts of the water soluble phosphine PTA (PTA = 1,3,5-triaza-7-phosphaadamantane)
Inorganic Chemistry Communications, 9, 4, 2006 | DOI

Article
Bolaño, S., Gonsalvi, L., Barbaro, P., Albinati, A., Rizzato, S., Gutsul, E., Belkova, N., Epstein, L., Shubina, E., Peruzzini, M.,
Synthesis, characterization, protonation studies and X-ray crystal structure of ReH<inf>5</inf>(PPh<inf>3</inf>)<inf>2</inf>(PTA) (PTA = 1,3,5-triaza-7-phosphaadamantane)
Journal of Organometallic Chemistry, 691, 4, 2006 | DOI

Article
Bolaño, S., Bravo, J., Castro, J., García-Fontán, S., Marín, M.C., Rodríguez-Seoane, P.,
New bromo-, triflato-, and hydridotricarbonylrhenium(I) complexes with diphosphinite ligands: Structural, spectral and protonation studies of various hydrides
Journal of Organometallic Chemistry, 690, 21-22, 2005 | DOI

Article
Bolaño, S., Bravo, J., García-Fontán, S.,
Mono- and dinuclear rhenium polyhydride complexes bearing the chelating ligand 1,2-bis(dicyclohexylphosphanyloxy)ethane
European Journal of Inorganic Chemistry, , 24, 2004 | DOI

Article
Bolaño, S., Gonsalvi, L., Zanobini, F., Vizza, F., Bertolasi, V., Romerosa, A., Peruzzini, M.,
Water soluble ruthenium cyclopentadienyl and aminocyclopentadienyl PTA complexes as catalysts for selective hydrogenation of ?,?-unsaturated substrates (PTA = 1,3,5-triaza-7-phosphaadamantane)
Journal of Molecular Catalysis A: Chemical, 224, 1-2, 2004 | DOI

Article
Bolaño, S., Bravo, J., Carballo, R., Freijanes, E., García-Fontán, S., Rodríguez-Seoane, P.,
Oxorhenium(V) complexes with bis-phosphinite chelating coligands (see abstract)
Polyhedron, 22, 13, 2003 | DOI

Article
Bolaño, S., Bravo, J., García-Fontán, S., Castro, J.,
Rhenium pentahydride complexes: Characterisation and protonation reactions. Crystal structure of ReH <inf>5</inf> L <sup>1</sup> L <sup>2</sup> (L <sup>1</sup> = Ph <inf>2</inf> PO(CH <inf>2</inf> ) <inf>2</inf> OPPh <inf>2</inf> ; L <sup>2</sup> = P(OCH <inf>3</inf> ) <inf>3</inf> , P(OCH <inf>2</inf> CH <inf>3</inf> ) <inf>3</inf&g
Journal of Organometallic Chemistry, 667, 1-2, 2003 | DOI

Article
Fernández-García, F., Bolao, S., Carballo, R., García-Fontán, S., Bravo, J.,
Reactions of [1,2-bis(diphenylphosphinite)ethane]bromotricarbonylrhenium(I) with phosphites, phosphonites and phosphinites. The crystal structure of [ReBr(CO)<inf>2</inf>{Ph<inf>2</inf>PO(CH<inf>2</inf>)<inf>2</inf> OPPh<inf>2</inf>}L?] [L? = P(OCH<inf>3</inf>)<inf>3</inf>, P(OC<inf>2</inf>H<inf>5</inf>)<inf>3</inf> and PPh(OC<inf>2</inf>H<inf>5</inf>)&l
Polyhedron, 20, 20, 2001 | DOI

Erratum
Bolao, S., Bravo, J., García-Fontán, S.,
Erratum: Polyhydride complexes of rhenium with the chelating ligand 1,2-bis(diphenylphosphinite)ethane (Inorganica Chimica Acta (2001) 315 (81) PII: S002016930100319X)
Inorganica Chimica Acta, 319, 1-2, 2001 | DOI

Article
Bolao, S., Bravo, J., García-Fontán, S.,
Polyhydride complexes of rhenium with the chelating ligand 1,2-bis(diphenylphosphinite)ethane
Inorganica Chimica Acta, 315, 1, 2001 | DOI

Article
Bolaño, S., Bravo, J., Carballo, R., García-Fontán, S., Abram, U., Vázquez-López, E.M.,
Synthesis and characterization of the bromide and hydride derivatives of rhenium(I) 1,2-bis(diphenylphosphinite)ethane complexes
Polyhedron, 18, 10, 1999 | DOI